What Is Octane?
Octane number is a measure of the resistance of gasoline to engine knocking (premature ignition). In the CFR octane engine, the sample is compared to reference fuels of known octane number. Two values are measured: RON represents the behavior at lower load and speed, MON represents the behavior at higher load and temperature.
Purpose of Octane
The purpose is to verify that gasoline can run in the engine without knocking and to demonstrate its compliance with the specification class. Knocking can cause permanent damage to the engine.
Which Products Is Octane Applied To?
- Unleaded gasoline (95, 98 octane)
- Ethanol blended gasolines
- Racing and special purpose fuels
- Refinery blending streams
- Oxygenate mixtures
In Which Sectors Is Octane Used?
Standards Related to Octane
- TS EN ISO 5164 (research octane number — RON)
- TS EN ISO 5163 (engine octane number — MON)
- ASTM D2699 / D2700
- TS EN 228 (gasoline specification)
Octane Conditions
- Engine conditions
- RON and MON are measured at different speed, mixture temperature and advance conditions
- Reference fuels
- Mixtures of isooctane and n-heptane
- Specimen
- Must be kept cold to prevent loss of volatile components
Equipment for Octane
- CFR octane engine (RON and MON configurations)
- Reference fuel sets
- Knock measurement system
- Refrigerated sample storage
Sample Requirements for Octane
- Sampling determines the validity of the result in fuel analysis: ISO 3170 (manual) and ISO 3171 (automatic in-line) define the sampling rules. The sample must be taken into a clean container of a suitable material, filled with no air gap, and kept cold for volatile products.
- The sample should be filled without leaving any air space and kept cold.
- Sufficient volume is required for the motor method
- Should be reported if oxygenate content is known
Duration of Octane
Engine measurement takes time due to engine calibration and reference comparisons; RON and MON are separate measurements and the total time reflects this.
Octane Procedure
- 1The CFR engine is configured and calibrated according to the relevant method.
- 2Reference fuel mixtures are prepared.
- 3The sample is fed to the engine and the knock intensity is measured.
- 4Matching is done with reference fuels.
- 5RON and MON are determined separately.
- 6The results are compared to the specification limit.
Octane Acceptance Criteria
The acceptance criterion comes from the relevant product specification and varies by season, market and class. Specification versions are updated; the limit values in force for your product are confirmed from the specification text at the quotation stage.
Evaluation of Results
RON and MON are evaluated together; The difference (sensitivity) shows the behavior of the fuel under different operating conditions. Ethanol significantly increases RON, but its effect on MON is more limited; Therefore, in blended fuels, the two values should be monitored together.
Octane Report
- Sample description and oxygenate content
- Applied standards
- RON and MON results
- Hassasiyet (RON−MON)
- Comparison against specification limits
Accreditation
EUROLAB holds internationally recognised accreditation obtained from accreditation bodies party to the IAF and ILAC multilateral recognition arrangements, under ISO/IEC 17025 for laboratory testing, ISO/IEC 17020 for inspection and surveillance, and ISO/IEC 17021-1 and ISO/IEC 17065 for system and product certification. This chain ensures the reports and certificates issued are accepted worldwide.
Whether this test can be offered within accredited scope depends on your product and the standard applied; since accreditation is method-based, the scope is confirmed in writing at the quotation stage.
Scope and authorisationsRelated Regulations
- 98/70/EC Fuel Quality Directive
Petroleum, Fuel and Oil Analysis — What Does This Testing Field Cover?
The section below describes the field that the Octane test belongs to; the conditions and acceptance criteria of this particular test are given in the sections above. The scope specific to your product is confirmed in writing at the quotation stage.
Petroleum, fuel and oil analysis determines whether a fluid meets its specification and how it behaves in use. Standards in this field consist largely of ASTM and EN publications, with a separate method defined for each parameter.
What distinguishes this family is that product specifications are written as PARAMETER LISTS. Specifications such as EN 590 (diesel), EN 228 (petrol), EN 14214 (biodiesel) and ISO 8217 (marine fuels) state for each parameter both the limit and the method by which that limit is to be measured. If the method changes the result may change too; the specification therefore binds the method as well, and the use of an "equivalent method" is possible only where the specification allows it.
On the fuel side, parameters describe three different properties of the product. Physical properties (density, viscosity, distillation curve, pour point, cloud point) determine pumpability and cold weather behaviour. Combustion properties (cetane number, octane number, calorific value) indicate performance in the engine. Contaminant and stability parameters (sulphur, water, sediment, oxidation stability, copper strip corrosion) affect both emissions and storage life.
Oil analysis is carried out for two different purposes and the two must not be confused. Analysis of NEW oil verifies the conformity of the product to its specification: viscosity index, additive content, flash point. Analysis of USED oil, by contrast, is done to read the condition of the machine — elemental analysis shows wear metals (iron, copper, chromium, aluminium), water and fuel contamination point to leaks, and oxidation and acid number determine the remaining life of the oil.
Used oil analysis is therefore a PREDICTIVE MAINTENANCE tool. The trend of samples taken at regular intervals is followed; it is the trend rather than a single result that is meaningful. Iron levels climbing over the course of months allow intervention before a failure occurs.
Marine fuels are the most active sub-body of the field. The global tightening of sulphur limits has brought new blended fuels onto the market; for these fuels stability, compatibility (whether two fuels form deposits when mixed) and catalytic fines content have become critical parameters.
Sampling is part of the result in this family too. A sample taken from the bottom of a tank shows different water and sediment content from one taken from the upper level; in commercial deliveries the sampling point and method are set by contract.
Method groups in this field
Physical properties
Density (oscillating U-tube and hydrometer), kinematic viscosity, distillation, pour and cloud point, flash point.
Combustion properties
Cetane number and cetane index, research and motor octane number, calorific value.
Sulphur and elements
Sulphur by UV fluorescence and XRF; elemental analysis and additive content by ICP.
Stability and corrosion
Oxidation stability, copper strip corrosion, water and sediment, filter blocking tendency.
Composition analysis
Boiling range distribution by gas chromatography, hydrocarbon types (FIA), benzene and aromatics content, fatty acid methyl ester content.
Used oil
Wear metals, contamination (water, fuel, soot), oxidation, acid and base number, change in viscosity.
Commonly confused in this field
- The specification binds the method as well; a result measured by a different method may not be accepted for specification conformity.
- A single result on used oil is not meaningful; the decision is made on the trend.
- The sampling point determines the result; the tank bottom and the upper level show different water and sediment.
- The cetane index is a calculated value and is not the same thing as a measured cetane number.
- Fuels blended with biodiesel behave differently in terms of storage life and microbial growth; classical diesel parameters are not sufficient.
- Mixing marine fuels from different sources can cause deposits; compatibility is assessed separately.
Which decisions these results support
- Conformity of a fuel lot to specification and commercial delivery
- Predictive maintenance decisions based on used oil analysis
- Determining parameters for customs and tax classification
- Quality verification after storage, blending and transport
- Compliance with sulphur limits under emissions legislation
Related Tests
Frequently Asked Questions About Octane
What is the pump octane?
In Europe, the declared value at stations is usually RON. In some markets, the average of RON and MON is used; That's why octane numbers in different countries cannot be directly compared.







